Thermo-Resistant Soft Glassy Suspensions of Polymeric Micellar Nanoparticles in Ionic Liquid

Gkermpoura, Sandra; Obiols-Rabasa, Marc; Iatridi, Zacharoula; Tsitsilianis, Constantinos
ACS Applied Materials & Interfaces, 2015
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We report the rheological and structural properties of a suspension comprising poly(ethylene oxide)–polystyrene–poly(ethylene oxide) core–shell micellar nanoparticles dispersed in 1-butyl-3-methylimidazolium hexafluorophosphate ionic liquid. A liquid to soft solid transition was observed at a copolymer concentration of 10 wt % above which an elastic soft material was formed, which was composed of non-ordered jammed core–shell micellar nanoparticles. In the soft solid state, a significant reduction in the size of the nanoparticles, approaching hard sphere behavior, was observed by small-angle X-ray scattering which is attributed to compression of the soft poly(ethylene oxide) coronas. The nonvolatile ionic liquid-based glassy soft solid formed exhibited remarkable thermal stability with a melting temperature of 141 °C at 20 wt % copolymer, which renders it suitable for applications involving elevated temperatures and/or reduced pressure where water-based formulations are inappropriate.

KEYWORDS: Nanoparticles, Polymers, Self-assembly